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Hydrogen is the simplest and most abundant element in the universe, and thus there are a variety of types in which it can be produced and subsequently stored. These types are based upon the processes of production. The following are the most common forms of hydrogen, emphasizing the production processes.
Green hydrogen
Green hydrogen is produced from renewable energy sources, such as solar and wind power through electrolysis—a process that uses electricity to split water into hydrogen and oxygen. This production method does not emit any carbon dioxide, making it the most environmentally friendly option for hydrogen production. Buyers looking for sustainable solutions will benefit from green hydrogen, as its production aligns with global efforts to reduce carbon emissions and combat climate change.
Blue hydrogen
Blue hydrogen is produced from natural gas through a process called steam methane reforming (SMR). In this process, natural gas is combined with steam to produce hydrogen and carbon dioxide. The carbon dioxide is then captured and stored, preventing it from entering the atmosphere. This method is seen as a transitional solution, as it still relies on fossil fuels, but with reduced emissions. Businesses in industries looking to lower their carbon footprint without completely shifting away from fossil fuels would find blue hydrogen to be a viable option.
Grey hydrogen
Hydrogen is commonly produced by steam methane reforming (SMR) which is the most common method of producing hydrogen. In this method, methane, which is natural gas, is combined with high-temperature steam to produce hydrogen and carbon monoxide. The carbon monoxide is further processed to convert it into carbon dioxide and more hydrogen through a method called the water-gas shift reaction. However, this method technically releases carbon emissions into the atmosphere, which negates the environmental-benefit-shift processes.
Black and brown hydrogen
Black and brown hydrogen are the least environmental-friendly production methods. Black hydrogen is produced from fossilized coal through a gasification process that turns coal into hydrogen and carbon by using water vapor and other chemicals. On the other hand, brown hydrogen is produced by gasifying biomass which is organic matter from plants and animals.
When choosing hydrogen, there are several key factors that buyers need to consider and understand in order to make an optimum choice. Here are these key factors:
Purity
Hydrogen gas purity is a critical factor across industries. For example, high-purity hydrogen is essential in the semiconductor and electronics industries to prevent contamination during sensitive manufacturing processes. In fuel cells, hydrogen fuel cells require purBecause fuel cells are designed to convert hydrogen into electricity, carbon impurities can poison the catalyst, leading to reduced efficiency or failure. Therefore, the purity level needed will depend on the application which will determine the required level of purity.
Storage and transport options
Hydrogen's low density and high energy content present unique challenges and considerations in terms of storage and transport. Buyers should assess these two factors based on costs, their operational needs, and logistics. For instance, compressed hydrogen is often transported in high-pressure cylinders or tanks, suitable for shorter distances, smaller quantities, or where infrastructure does not exist. Liquid hydrogen, which is extremely energy-dense, requires specialized cryogenic equipment for transport and storage, making it more costly but suitable for larger operations or longer distances. Other methods of transport include hydrogen pipelines, dedicated hydrogen carriers, blending with natural gas, liquid organic hydrogen carriers, and adsorbed or covenantally bonded hydrogen, although some of these methods are still in their infancy. Buyers should evaluate these storage and transport systems based on their operational cost, efficiency, safety, and reliability.
Application requirements
The intended application of hydrogen will significantly impact the buyer's choice. Industries like petroleum refining and ammonia production have established systems that readily accommodate lower-purity hydrogen. However, high-purity hydrogen is necessary for sectors like electronics manufacturing, pharmaceutical processes, and fuel cell technologies requiring strict contamination controls. Powering fuel cell vehicles requires premium hydrogen. Hence, the application needs will dictate the required hydrogen type and purity.
Regulatory compliance
The handling, storage, and use of hydrogen are subjected to stringent regulations and safety standards, not only because of its flammability but also because its utilization opens up opportunities for environmental sustainability. Buyers, therefore, must comply with all local, national, and international regulations pertaining to hydrogen use in their industry. These regulations could be related to emission limits, occupational safety, or transport. This understanding will prevent buyers from incurring legal penalties and fines while ensuring safe and sustainable operations.
Hydrogen is a colorless, odorless gas when in its natural state, and thus, very light and the smallest element. Therefore, it has a number of features and characteristics that not only affect its behavior in the environment but also these features influence and determine the production, storage, transport, and usage of hydrogen. Here are these features:
Energy content and flammability
Hydrogen gas has an extremely high energy content, and this is more than that of any other gas. This is because it has a very high heat content. HHV is the hydrogen's volume and amount of heat content, and hydrogen's HHV is approximately 141.85 MJ/kg. Hydrogen is also highly flammable, with a narrow range of concentrations in the air, approximately 4% to 75% by volume. This makes it very explosive. This high energy content and flammability make it a very good candidate for fuel cells.
Density
It is the lightest element, so hydrogen has a very large density. This makes it very good because, in a storage system, more volume means that more energy can be packed into the system. For instance, in the case of compressed hydrogen, the pressure is a storage technique that increases the density of hydrogen; hence, heavier facilities can achieve higher HC by using compressed hydrogen. This also improves vehicles' distance and efficiency with on-board fuel tanks.
ISotopes
There are three major isotopes of hydrogen, and all of them are variants of hydrogen. These variations are based on the number of neutrons in the element. They are protium, deuterium, and tritium. Protium has no neutrons, hydrogen, which is the most abundant, has one neutron, deuterium, and tritium, which has two neutrons. Tritium is radioactive, and it decays into helium. This typically takes about 12.32 years.
Production methods
Hydrogen gas can be produced using various methods. Each of these methods is called a hydrogen-production process. These processes include water electrolysis, fossil fuel reforming like natural gas, and coal gasification.
Hydrogen has a variety of industrial applications, and each application has a unique method of utilization. Here are the most common uses of hydrogen:
Fuel cells
Fuel cells convert the chemical energy of hydrogen directly into electricity through electrochemical reactions. This produces only water vapor as a by-product. There are many types of fuel cells. These include PEFC (proton exchange membrane fuel cells), MCFC (molten carbonate fuel cells), etc. Each of these cell types uses hydrogen in the same way, but their application is different. Hydrogen's versatility as a power source enables a wide range of applications, from automotive to stationary power systems.
Industrial processes
Hydrogen is commonly used in industrial applications, especially ammonia production through the Haber-Bosch process. Here, hydrogen is combined with nitrogen at high pressures and temperatures to produce ammonia (NH3), which is the primary and major ingredient in synthetic fertilizer. Speaking of fertilizers, hydrogen is also utilized in the petroleum refining sector in a process called hydrocracking. Here, heavy crude oil is mixed with hydrogen to break down the molecules to produce lighter, more valuable products like gasoline and diesel. Lastly, hydrogen is also used in metallurgical industries, where it is used for reducing iron oxide ores to produce pure iron for use in steel production.
Energy carrier
Hydrogen is called the cleanest energy carrier because, unlike energy-producing elements, it does not produce any emissions. On the contrary, for instance, electricity generation using coal will produce harmful emissions like carbon monoxide, but if the electricity is converted to hydrogen gas through water electrolysis, no emission will be made. Thus, this makes hydrogen a carbon-free fuel that can be produced from any source.
Heating systems
Hydrogen can be used for hybrid heating systems that burn hydrogen and natural gas to produce heat for residential and industrial furnaces. Moreover, hydrogen can be completely burned to provide hydrogen heating. Another name for this is hydrogen home, which is still being trialed in the UK. It aims to convert domestic appliances, heating, and cooking systems to use only pure hydrogen, eliminating the emission of this utility element.
There are three key safety measures that are to be taken to avoid the flammable and explosive nature of hydrogen. These are proper ventilation, the use of safety equipment such as goggles and gloves, and the use of hydrogen detectors. Proper ventilation will ensure that if there is any leak, the concentration of the gas will not reach the flammability threshold. Safety equipment will protect personnel from harm in case any explosions occur. Lastly, hydrogen detectors will constantly sense the presence of hydrogen to enable quick action once it is detected, hence minimizing its effects.
The level of purity directly impacts the sensitivity of the process. For example, hydrogen is needed in atomic hydrogen welding, and for this, only a purity of 99.9% is required. Conversely, ammonia production can use 95%-97% hydrogen because that process cannot tolerate impurities. 95%-97% hydrogen can suffice for processes like hydrocarbon processing and chemical manufacturing. Nevertheless, hydrogen for high-tech applications like fuel cells, semiconductors, and platinum metal refining must be 99.999% pure.
This all depends on the type of hydrogen. Green hydrogen has no negative environmental impacts because it is produced from renewable energy sources that do not emit greenhouse gases. Conversely, grey, black, and brown hydrogen emit greenhouse gases because they are produced from fossil fuels or coal, which causes global warming and climate change.
Hydrogen is more energy-efficient than other sources or mediums. Unlike gasoline, which uses wood, coal, or fossil fuels, hydrogen is used in hydrogen-fueled internal combustion engines. Here, rather than burning it to convert it to kinetic energy like gasoline, which is less efficient because it produces emissions in the process of conversion. Nevertheless, electrochemical systems like fuel cells are the most efficient because they convert hydrogen to kinetic energy through electrochemical reactions that hardly emit any. Hence, hydrogen is more efficient than other energy medium systems.